全文获取类型
收费全文 | 36570篇 |
免费 | 3966篇 |
国内免费 | 2563篇 |
专业分类
电工技术 | 2828篇 |
技术理论 | 8篇 |
综合类 | 5386篇 |
化学工业 | 2786篇 |
金属工艺 | 911篇 |
机械仪表 | 2346篇 |
建筑科学 | 3677篇 |
矿业工程 | 1269篇 |
能源动力 | 1393篇 |
轻工业 | 515篇 |
水利工程 | 1050篇 |
石油天然气 | 906篇 |
武器工业 | 605篇 |
无线电 | 3288篇 |
一般工业技术 | 4238篇 |
冶金工业 | 2194篇 |
原子能技术 | 330篇 |
自动化技术 | 9369篇 |
出版年
2024年 | 66篇 |
2023年 | 564篇 |
2022年 | 748篇 |
2021年 | 998篇 |
2020年 | 1155篇 |
2019年 | 1042篇 |
2018年 | 1074篇 |
2017年 | 1233篇 |
2016年 | 1338篇 |
2015年 | 1360篇 |
2014年 | 2122篇 |
2013年 | 2557篇 |
2012年 | 2327篇 |
2011年 | 2662篇 |
2010年 | 2160篇 |
2009年 | 2237篇 |
2008年 | 2329篇 |
2007年 | 2420篇 |
2006年 | 2256篇 |
2005年 | 1971篇 |
2004年 | 1615篇 |
2003年 | 1332篇 |
2002年 | 1137篇 |
2001年 | 923篇 |
2000年 | 772篇 |
1999年 | 673篇 |
1998年 | 510篇 |
1997年 | 461篇 |
1996年 | 394篇 |
1995年 | 391篇 |
1994年 | 320篇 |
1993年 | 274篇 |
1992年 | 246篇 |
1991年 | 175篇 |
1990年 | 149篇 |
1989年 | 169篇 |
1988年 | 129篇 |
1987年 | 71篇 |
1986年 | 91篇 |
1985年 | 69篇 |
1984年 | 68篇 |
1983年 | 49篇 |
1982年 | 56篇 |
1981年 | 43篇 |
1980年 | 31篇 |
1979年 | 33篇 |
1978年 | 30篇 |
1977年 | 26篇 |
1964年 | 26篇 |
1955年 | 36篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
72.
Mariame Amine Abdellatif Kobbane Jalel Ben‐Othman Abdellaziz Walid 《International Journal of Communication Systems》2020,33(8)
Recently, academic and industrial research communities are paying more explicit attention to the 5G multiple radio access technology ultra‐dense networks (5G multi‐RAT UDNs) for boosting network capacity, especially in UD urban zones. To this aim, in this paper, we intend to tackle the user association problem in 5G multi‐RAT UDNs. By considering the decoupled uplink/downlink access (DUDA), we divide our user association problem into two distinct subproblems representing, respectively, the uplink and the downlink channels. Next, we formulated each one as a nonlinear optimization problem with binary variables. Then, to solve them, we were restricted by the hard complexity, as well as the hard feasibility of centralized user association schemes. Thus, to resolve our user association problem in a reasonable time and distributed manner, we formulated each subproblem as a many‐to‐one matching game based on matching theory. Next, we provide two fully distributed association algorithms to compute the uplink and downlink stable matching among user equipments (UEs) and base stations (BSs). Simulation results corroborate our theoretical model and show the effectiveness and improvement of our achieved results in terms of the overall network performance, quality of service (QoS), and energy efficiency (EE) of UEs. 相似文献
73.
铜-配体(L)-三肽组成的三元复合物[Cu(L)M]2+,其中,L表示4′-氯-2,2′:6′,2″-三联吡啶(缩写为4Cl-tpy);M表示酪氨酰-甘氨酰-色氨酸(YGW)及其修饰型三肽(CH3CO-YGW-OCH3,缩写 Ac-YGW-OMe)。使用该复合物,通过碰撞诱导解离 (collision-induced dissociation, CID)产生两种自由基离子 ([YGW]·+和[Ac-YGW-OMe]·+)。采用串联质谱结合密度泛函理论 (density functional theory, DFT)得到气相稳定结构,并研究其气相解离行为。研究结果表明,[YGW]·+和[Ac-YGW-OMe]·+的气相解离行为截然不同,[YGW]·+主要产生[M-CO2-116]+和[M-CO2]·+碎片离子;而[Ac-YGW-OMe]·+在气相中主要产生[M-CH3OH]·+碎片离子。推测这两种离子的气相裂解机理分别为:[YGW]·+羧基上的质子重排到多肽骨架中羰基氧上,经历 Cα-C键的断裂产生[M-CO2]·+、断裂色氨酸侧链 Cβ-Cγ键产生[M-CO2-116]+离子;[Ac-YGW-OMe]·+则先经历质子重排到酯基氧上,然后经过C-O酯键的断裂形成[M-CH3OH]·+离子。参与重排的质子可能有3个来源:Ac-YGW-OMe中甘氨酸的Cα-H、色氨酸的Cα-H 或Cβ-H,该机理有待进一步验证。本研究将为其他类型多肽及衍生物的结构及气相反应机理研究提供参考。 相似文献
74.
In this study, we proposed a model for the morphological structure of electrospun membranes; it was different from the random distribution of fibers in a nonwoven. On the basis of our observation and analysis of the jet path by a high‐speed camera and the electrospun membranes by scanning electron microscopy, we proposed the base circle/deposition circle model of electrospun membranes. The base circle was used to position the deposition circles. The deposition circles, distributed on or around the base circle at a specific proportion, represented the distribution of the electrospun fibers on the collector. The pore characteristics and fiber distribution were compared between the electrospun membrane and simulated membranes with different spinning times; this verified that they had similar distribution trends. A membrane was simulated with a similar magnification ratio to the actual membrane. This further verified the model. This model could be used for the homogeneity simulation of an electrospun membrane in multinozzle electrospinning, and this may be helpful for predicting electrospun membranes in practical applications. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45653. 相似文献
75.
With the rapid development of artificial intelligence (AI), AI anxiety has emerged and is receiving widespread attention, but research on this topic is not comprehensive. Therefore, we investigated the dimensions of AI anxiety using the theoretical model of integrated fear acquisition and a questionnaire survey. A total of 494 valid questionnaires were recovered. Through a first-order confirmatory factor analysis (CFA), a factor model of AI anxiety was constructed, and eight factors of AI anxiety were verified. Then, a second-order CFA was applied to verify the adaptation of the factor structure of AI anxiety to fear acquisition. We identified four dimensions of AI anxiety and proposed a theory of AI anxiety acquisition that illustrates four pathways of AI anxiety acquisition. Each pathway includes two factors that cause AI anxiety. We conclude by analyzing the limitations of current AI anxiety research and proposing a broader research agenda for AI anxiety. 相似文献
76.
The recent trend of aging population, not to mention the unprecedented pandemic, draws great attention from the general public about health concerns. Since healthcare information technology is different from non-healthcare information technology, additional contexts should be properly incorporated into technology acceptance research to accurately identify influential factors affecting the acceptance of wearable healthcare technology. Thus, we selectively reconfigured factors from health, privacy, and socio-demographic contexts to formulate a health-aware acceptance model. Then, it was empirically analyzed using structural equation modeling. Based on the results, whereas privacy concerns were directly associated with intention to use wearable healthcare technology, health concerns were not. Moreover, age had a moderating effect on social influence and facilitating conditions. These findings suggest valuable insights that the adoption rate of healthcare technology is increased by 1) keeping personal information securely, 2) facilitating social interaction among users, and 3) offering intuitive user experience for elderly people. 相似文献
77.
Khalid Quertite Hanna Enriquez Nicolas Trcera Yongfeng Tong Azzedine Bendounan Andrew J. Mayne Gérald Dujardin Pierre Lagarde Abdallah El kenz Abdelilah Benyoussef Yannick J. Dappe Abdelkader Kara Hamid Oughaddou 《Advanced functional materials》2021,31(7):2007013
Silicene, a new 2D material has attracted intense research because of the ubiquitous use of silicon in modern technology. However, producing free-standing silicene has proved to be a huge challenge. Until now, silicene could be synthesized only on metal surfaces where it naturally forms strong interactions with the metal substrate that modify its electronic properties. Here, the authors report the first experimental evidence of silicene nanoribbons on an insulating NaCl thin film. This work represents a major breakthrough, for the study of the intrinsic properties of silicene, and by extension to other 2D materials that have so far only been grown on metal surfaces. 相似文献
78.
The effect of charge on the dihydrogen storage capacity of Sc2–C6H6 has been investigated at B3LYP-D3/6-311G(d,p) level. The neutral system Sc2–C6H6 can store 8H2 with gravimetric density of 8.76 wt %, and one H2 dissociates and bonds atomically on the scandium atom. The adsorption of 8H2 on Sc2–C6H6 is energetically favorable below 155 K. The atom-centered density matrix propagation (ADMP) molecular dynamics simulations show that Sc2–C6H6 can adsorb 3H2 within 1000 fs at 300K. Compared with Sc2–C6H6, the charged systems can adsorb more hydrogen molecules with higher gravimetric density, and all the H2 are adsorbed in the molecular form. The gravimetric densities of Sc2–C6H6+ and Sc2–C6H62+ are 9.75 and 10.71 wt%. Moreover, the maximum adsorption of charged systems are favorable in wider temperature range. Most importantly, the ADMP-MD simulations indicate that Sc2–C6H62+ can adsorb 6 hydrogen molecules within 1000 fs at 300K. It can be found that the gravimetric density (6.72 wt%) of Sc2–C6H62+ still exceeds the target of US Department of Energy (DOE) under ambient conditions. 相似文献
79.
Wei Lai Lihong Ge Huaming Li Yilin Deng Bin Xu Bo Ouyang Erjun Kan 《International Journal of Hydrogen Energy》2021,46(53):26861-26872
The electrochemical water splitting to produce H2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)2 heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H2-evolving current density of 10 mA/cm2 and 153 mV at 100 mA/cm2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance. 相似文献
80.
《Information & Management》2020,57(4):103218
As social media continues to transform firm–customer interactions, firms must leverage customer reactions to generate actionable insights, especially in contexts (e.g., crisis events) where customer reactions are critical. Using the justice theory, we categorize customer reactions of two firms, Home Depot and Target, during the time-frame of a security hack to understand key themes/topics. We then map the themes/topics to customer sentiments in those reactions. We found that customers associate justice with simple procedures than the experience of dealing with the firm. In addition, it is critical for firms to carefully assess and control customer sentiments on social media during crisis events. 相似文献